Material Safety Data Sheet

1. CHEMICAL PRODUCT
General Product Name: Biodiesel
Synonym: Methyl Ester
Product Description: Methyl ester
CAS Number: 67784-80-9

2. COMPOSITION / INFORMATION ON INGREDIENTS
This product contains no hazardous ingredients as defined under the Canadian Hazardous Products Act S.C. 1987, C.30 (Part 1)

3. HEALTH HAZARD DATA
INHALATION : Negligible unless heated to produce vapors. Vapors or finely misted materials may irritate the mucous membranes and cause irritation, dizziness, and nausea. Remove to fresh air.
EYE CONTACT : May cause irritation. Irrigate eye with water for at least 15 to 20 minutes. Seek medical attention if symptoms persist.
SKIN CONTACT : Not classified as a primary skin irritant or corrosive material. Prolonged or repeated contact is not likely to cause significant skin irritation.
INGESTION : Ingestion incidental to industrial exposure is not anticipated to be hazardous. Similar products have an acute oral toxicity LD50 >17.4g/Kg (Albino rats).

4. FIRST AID MEASURES
INHALATION : Remove victim to fresh air. Seek medical attention.
EYE CONTACT : Flush eyes with plenty of cool water for 15 to 20 minutes. Do not let victim rub eyes. Seek medical attention if irritation persists.
SKIN CONTACT : Wash exposed areas with soap and water.
INGESTION : Call a physical or poison control center promptly.

5. FIRE FIGHTING MEASURES
FLASH POINT (METHOD USED): >100o C (ASTM93)
FLAMMABLE LIMITS IN AIR, % BY VOL. LOWER Not applicable
FLAMMABLE LIMITS IN AIR, % BY VOL. UPPER Not applicable 3
FIRE FIGHTING PROCEDURES AND PRECAUTIONS : Use water spray (fog), dry chemical, foam or carbon dioxide. Water stream can splash burning liquid and spread fire, but may be used to keep fire exposed containers cool.
UNUSUAL FIRE AND EXPLOSION HAZARDS : Soaked rags can cause spontaneous combustion if not handled properly. Keep soaked rags in an approved container or let dry individually in a well ventilated area. Before disposal, wash rags with soap and water and dry in a well ventilated area. Firefighters should wear self-contained breathing apparatus when there is the possibility of exposure to smoke, fumes or hazardous decomposition products.

6. ACCIDENTAL RELEASE MEASURES / SPILL CLEAN-UP PROCEDURES
Remove sources of ignition and contain the spill to the smallest area possible. Stop leak if possible. Pick up small spills with absorbent materials such as paper towels, oil absorbent granular products, sand or dirt. Wash hard surfaces with a safety solvent or detergent to remove remaining oil film or a slippery surface will result. Recover large spills for salvage or disposal. Follow municipal, provincial and federal disposal regulations.

7. HANDLING AND STORAGE
Keep in closed containers between 10o C and 50o C.
Keep away from oxidizing agents, excessive heat, and ignition sources.
Store out of sun.
Store and use in well ventilated areas.
Do not store or use near heat, spark or flame.

8. EXPOSURE CONTROL / PERSONAL PROTECTION
RESPIRATORY PROTECTION : Handle in the presence of adequate ventilation. If vapors or mists are generated, wear NIOSH approved organic/mist respirator.
PROTECTIVE CLOTHING : Safety glasses, goggles, or face shield recommended to protect eyes from mists or splashing. PVC coated gloves recommended to prevent skin contact. Launder contaminated clothing before reuse.

9. PHYSICAL AND CHEMICAL PROPERTIES
Boiling point, 760 mm Hg:>200o C
Specific Gravity : 0.87 at 25o C
Vapor Pressure, mm HG:< 2
Vapor density, Air = 1:>1
Volatiles, % by volume: < 2
Solubility in H2O, % by volume : insoluble
Evaporation Rate, Butyl Acetate = 1 :< 1
Appearance and Odor: pale yellow liquid at room temp., mild odor

10. STABILITY AND REACTIVITY
GENERAL : This product is stable and hazardous polymerization will not occur.
INCOMPATIBLE MATERIALS AND CONDITIONS TO AVOID : Strong oxidizing agents, strong reducing agents, strong acids, strong bases, strong alkalis, strong mineral acids.
HAZARDOUS DECOMPOSITION PRODUCTS : Decomposition may produce oxides of carbon, nitrogen, and various other hydrocarbons.

11. TRANSPORTATION INFORMATION
UN HAZARD CLASS: N/A
NMFC (National Motor Freight Classification)
PROPER SHIPPING NAME: FATTY ACID ESTER
IDENTIFICATION NUMBER: 144920
SHIPPING CLASSIFICATION: 65

12. OTHER INFORMATION
The information presented herein is believed to be factual and accurate to the best of the company’s knowledge. However, no representation, warranty or guarantee of any kind, express or implied, is made as to its accuracy, reliability or completeness and we assume no responsibility for any loss, damage or expense, direct or consequential, arising out of its use. It is the user’s responsibility to satisfy himself as to the suitableness and completeness of this information for his own particular use.

Notes and Remarks : For the analysis performed, the Results on your sample comply with requirements of ASTM D6751-02 Standard Specification for Biodiesel Fuel (B100) Blend Stock for Distillate Fuels.